Diffusiophoresis in a near-critical binary fluid mixture

نویسندگان

چکیده

We consider placing a rigid spherical particle into binary fluid mixture in the homogeneous phase near demixing critical point. The surface is assumed to have short-range interaction with each component and attract one more than other. Owing large osmotic susceptibility, adsorption layer, where preferred concentrated, can be of significant thickness. This causes motion under an imposed composition gradient. Thus, diffusiophoresis emerges from mechanism which has not been considered so far. calculate how mobility depends on temperature size.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Critical End Point Behaviour in a Binary Fluid Mixture

We consider the liquid-gas phase boundary in a binary fluid mixture near its critical end point. Using general scaling arguments we show that the diameter of the liquid-gas coexistence curve exhibits singular behaviour as the critical end point is approached. This prediction is tested by means of extensive Monte-Carlo simulations of a symmetrical Lennard-Jones binary mixture within the grand ca...

متن کامل

Self-Diffusiophoresis of Janus Particles in Near-Critical Mixtures.

We theoretically study the self-propulsion of a laser-heated Janus particle in a near-critical water-lutidine mixture, and we relate its velocity v_{p} and squirmer parameter β to the wetting properties of its two hemispheres. For nonionic surface forces, the particle moves the active cap at the front, whereas a charged hydrophilic cap leads to backward motion, in agreement with the experiment....

متن کامل

Critical Fluctuations of a Confined Binary Mixture

Exploiting the mapping between a binary mixture and the Ising model we have analyzed the critical fluctuations by means of the density-matrix renormalization group technique. The calculations have been carried out for a two-dimensional Ising strip subject to equally strong surface fields. It was found that the critical Casimir force has significantly different behavior on opposite sides of the ...

متن کامل

Observation of an anomalous adsorption in a critical binary mixture

2014 We have experimentally demonstrated the existence of a new critical anomaly in a binary mixture, due to the preferential adsorption of one of the components onto a solid wall. J. Physique LETTRES 43 (1982) L-133 L-136 Classification Physics Abstracts 64.70J 68.45 1 er MARS 1982, 1. Interaction of a binary mixture with a surface. A mixture of two fluids which exhibits a critical phase separ...

متن کامل

Solvation effects in near-critical binary mixtures.

A Ginzburg-Landau theory is presented to investigate solvation effects in near-critical polar fluid binary mixtures. Concentration dependence of the dielectric constant gives rise to a shell region around a charged particle within which solvation occurs preferentially. As the critical point is approached, the concentration has a long-range Ornstein-Zernike tail representing strong critical elec...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Physics of Fluids

سال: 2022

ISSN: ['1527-2435', '1089-7666', '1070-6631']

DOI: https://doi.org/10.1063/5.0082991